Health, Preparations
Potassium dichromate - physicochemical properties and application
Potassium dichromate is a non-tracing crystal of predominantly orange color (sometimes reddish), which dissolve well in the aquatic environment and resemble the thinnest needles or plates in shape. When interacting with a substance, the aqueous solution acquires an acidic reaction.
Potassium dichromate is a highly toxic, carcinogenic substance and the strongest oxidant. Spray solutions can destroy the skin, cartilage tissue, and inhalation of vapors - respiratory tract.
At a temperature of about 1300 ° C, as a result of the exchange reaction of sodium dichromate and potassium chloride, potassium dichromate is obtained, the formula of which is K 2 Cr 2 O 7 :
2KCl + Na 2 Cr 2 O 7 → K 2 Cr 2 O 7 + 2NaCl.
A red-yellow solution of potassium dichloride stains the litmus paper in a pale red color. With further boiling, the chemical solution acquires a characteristic dark red color. When the temperature reaches 398 ° C, potassium dichromate begins to melt and turns into a liquid of a dark brown color, which upon subsequent cooling solidifies and crystallizes. Above 500 ° C, the substance completely decomposes to form oxygen, chromium oxide and potassium chromate.
Physicochemical properties of potassium dichromate
Index | unit of measurement | Value |
crystal cell | Triclinic or monoclinic | |
refraction | 1,738 | |
Molecular weight | 294.19 | |
Specific gravity | G / cm 3 | 2,684 |
boiling temperature | O C | 398 |
melting temperature | O C | Completely decomposes at 500 |
Solubility in 100 grams of water at a temperature of: | D | |
0 o C | 4.7 | |
20 o C | 11.1 | |
100 ° C | 102 |
Rules for storage and transportation of a chemical substance of an increased hazard class
Packing of a chemical belonging to the first class of danger
Technical potassium dichromate is packed in specially designed steel drums, as well as polyethylene bags consisting of five layers, weighing up to 50 kg. It is allowed to pack in soft containers of specialized purpose for one-time use.
The established hazard class for a chemical
Technical potassium dichromate is explosive and fire-hazardous. By the degree of impact on the human body, he was given the first class of danger. When working with a chemical, it is necessary to observe safety precautions, to be extremely cautious and attentive, and personal protective equipment for the skin and respiratory organs should be used.
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